4.4.1.10 Reaction of Brass with Chlorine Gas

1.A heated piece of brass is placed in a flask containing chlorine 2.A white zinc chloride fog is immediately produced
A heated piece of brass is placed in a flask containing chlorine A white zinc chloride fog is immediately produced
3.The color is light brown due to copper chloride 4.Reaction product: corroded brass
The color is light brown due to copper chloride Reaction product: corroded brass

Photo 1:Experimental setup: An Erlenmeyer flask is filled with chlorine. A piece of brass is simultaneously heated with a Bunsen burner. The hot brass slug is then placed in the flask.
Photo 2:A white zinc chloride fog is immediately produced. Brass is a zinc-copper alloy. The zinc it contains reacts with chlorine according to:

Zn + Cl2        > ZnCl2
Photo 3:Shortly thereafter, brown copper chloride fog is produced in a similer manner. Copper reacts with chlorine gas analagous to zinc, only more slowly.
Photo 4:Elemental copper remains as a reaction product, since it takes a longer time to react with chlorine. The zinc that was previously contained in the brass has (at least on the outer surface) reacted completely with the chlorine.

Back to the index